Table 8. COPs and COFs Used as Sensors for Various Amines and Ammonia.
material | amine analyte | sensing mechanism | LOD | KSV (M–1) | ref. |
---|---|---|---|---|---|
F-CTF-3 | phenylamine | static quenching | 11.7 nM | 8.01 × 105 | (112) |
F-CTF-3 | p-phenylenediamine | static quenching | 1.47 nM | 6.36 × 106 | (112) |
F-CTF-3 | 1-naphthylamine | static quenching | 26.2 nM | 3.57 × 105 | (112) |
P7-COP | n-propyl amine | PET | 114 ppm | n/a | (111) |
P7-COP | n-hexylamine | PET | 4.0 ppm | n/a | (111) |
P7-COP | diethylamine | PET | 190 ppm | n/a | (111) |
P7-COP | dipropylamine | PET | 0.036 ppb | n/a | (111) |
P7-COP | aniline | PET | 0.52 ppb | n/a | (111) |
P7-COP | o-toluidine | PET | 0.55 ppt | n/a | (111) |
COP-1 | NH3 | ICT | 5.9 × 10–4 | n/a | (116) |
P1 | p-phenylenediamine | PET (quenching) | 171 nM | n/a | (115) |
P2 | aniline | PET (quenching) | 81 nM | n/a | (115) |
P2 | triethylamine | turn-on fluorescence | 43 nM | n/a | (115) |
TPE-Ph COF | NH3 | AIE | n/a | 4.44 × 105 | (117) |