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. 2021 Apr 7;6(4):1461–1481. doi: 10.1021/acssensors.1c00183

Table 8. COPs and COFs Used as Sensors for Various Amines and Ammonia.

material amine analyte sensing mechanism LOD KSV (M–1) ref.
F-CTF-3 phenylamine static quenching 11.7 nM 8.01 × 105 (112)
F-CTF-3 p-phenylenediamine static quenching 1.47 nM 6.36 × 106 (112)
F-CTF-3 1-naphthylamine static quenching 26.2 nM 3.57 × 105 (112)
P7-COP n-propyl amine PET 114 ppm n/a (111)
P7-COP n-hexylamine PET 4.0 ppm n/a (111)
P7-COP diethylamine PET 190 ppm n/a (111)
P7-COP dipropylamine PET 0.036 ppb n/a (111)
P7-COP aniline PET 0.52 ppb n/a (111)
P7-COP o-toluidine PET 0.55 ppt n/a (111)
COP-1 NH3 ICT 5.9 × 10–4 n/a (116)
P1 p-phenylenediamine PET (quenching) 171 nM n/a (115)
P2 aniline PET (quenching) 81 nM n/a (115)
P2 triethylamine turn-on fluorescence 43 nM n/a (115)
TPE-Ph COF NH3 AIE n/a 4.44 × 105 (117)