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. 2020 Feb 5;11(10):2770–2782. doi: 10.1039/c9sc05268b

Inverse-trans-influence calculated from eqn (1) for the MBr3(OPcy3)3 (M = Am, Nd, Pr, Ce, La) series6.

MBr3(OPcy3)3 Am Nd Pr Ce La
Radius (Å)a 0.975 0.983 0.99 1.01 1.032
ITIM–Br 98.8(2) 98.9(2) 98.8(2) 99.0(2) 99.1(1)
ITIM–O 98.2(2) 98.6(3) 98.4(2) 98.6(1) 99.0(3)
a

6-Coordinate Shannon ionic radius.