Table 2. Box–Behnken Design Matrix with Three Independent Variables for the Experimental and Predicted Pd Selectivity Coefficient Values.
| independent
variables |
dependent variable |
|||||||
|---|---|---|---|---|---|---|---|---|
| coded
values |
real values |
selectivity coefficient |
||||||
| run | X1 | X2 | X3 | ECH (%) | pH | ECH (%) | βexp | βpred |
| 1 | –1 | –1 | 0 | 0.10 | 1.0 | 0.55 | 100.98 ± 0.70 | 98.74 |
| 2 | +1 | –1 | 0 | 1.00 | 1.0 | 0.55 | 18.04 ± 1.21 | 18.97 |
| 3 | –1 | +1 | 0 | 0.10 | 2.4 | 0.55 | 67.71 ± 0.17 | 66.78 |
| 4 | +1 | +1 | 0 | 1.00 | 2.4 | 0.55 | 19.45 ± 0.94 | 21.69 |
| 5 | –1 | 0 | –1 | 0.10 | 1.7 | 0.10 | 62.42 ± 2.03 | 64.51 |
| 6 | +1 | 0 | –1 | 1.00 | 1.7 | 0.10 | 19.09 ± 0.06 | 18.00 |
| 7 | –1 | 0 | +1 | 0.10 | 1.7 | 1.00 | 90.12 ± 2.36 | 91.21 |
| 8 | +1 | 0 | +1 | 1.00 | 1.7 | 1.00 | 14.96 ± 1.83 | 12.87 |
| 9 | 0 | –1 | –1 | 0.55 | 1.0 | 0.10 | 31.63 ± 2.35 | 31.78 |
| 10 | 0 | +1 | –1 | 0.55 | 2.4 | 0.10 | 26.23 ± 0.15 | 25.07 |
| 11 | 0 | –1 | +1 | 0.55 | 1.0 | 1.00 | 49.32± 1.20 | 50.48 |
| 12 | 0 | +1 | +1 | 0.55 | 2.4 | 1.00 | 28.10 ± 0.71 | 27.95 |
| 13 | 0 | 0 | 0 | 0.55 | 1.7 | 0.55 | 28.12 ± 0.41 | 27.06 |
| 14 | 0 | 0 | 0 | 0.55 | 1.7 | 0.55 | 24.72 ± 1.85 | 27.06 |
| 15 | 0 | 0 | 0 | 0.55 | 1.7 | 0.55 | 27.23 ± 0.56 | 27.06 |
| 16 | 0 | 0 | 0 | 0.55 | 1.7 | 0.55 | 26.91 ± 0.42 | 27.06 |
| 17 | 0 | 0 | 0 | 0.55 | 1.7 | 0.55 | 28.31 ± 2.10 | 27.06 |