Table 1. Theoretical Parameters of the Studied Kinetic and Isotherm Models in Addition to the Thermodynamic Parameters.
model | parameters | DI | CS/D |
---|---|---|---|
pseudo-first-order | K1 (min–1) | 0.3557 | 0.3817 |
qe(cal) (mg/g) | 365.4 | 573 | |
R2 | 0.98 | 0.91 | |
X2 | 0.65 | 4.3 | |
pseudo-second-order | k2 (g mg–1 min–1) | 3.4 × 10–4 | 2.5 × 10–4 |
qe(cal) (mg/g) | 386.5 | 523 | |
R2 | 0.922 | 0.93 | |
X2 | 1.54 | 2.8 | |
Langmuir | qmax (mg/g) | 440.39 | 765.5 |
b (L/mg) | 4.09 × 10–4 | 0.0076 | |
R2 | 0.93 | 0.91 | |
X2 | 4.14 | 4.65 | |
RL | 0.75–0.92 | 0.141–0.396 | |
Freundlich | 1/n | 0.5 | 0.39 |
kF (mg/g) | 16.4 | 47.7 | |
R2 | 0.87 | 0.88 | |
X2 | 5.63 | 5.86 | |
D–R model | β (mol2/KJ2) | 0.0084 | 0.0079 |
qm (mg/g) | 396 | 574.6 | |
R2 | 0.86 | 0.84 | |
X2 | 6.78 | 6.88 | |
E (KJ/mol) | 7.71 | 7.95 | |
ΔGo (kJ mol–1) | 303.15 | –22.51 | –24.55 |
308.15 | –22.84 | –24.77 | |
313.15 | –22.98 | –25.03 | |
318.15 | –23.10 | –25.23 | |
323.15 | –23.28 | –25.40 | |
ΔH° (kJ mol–1) | –11.6 | –11.46 | |
ΔS° (J K–1 mol–1) | 36.27 | 43.22 |