Skip to main content
. 2020 Apr 21;11(18):4817–4827. doi: 10.1039/d0sc01561j

Catalytic dehydrocoupling of Me2NHBH3 by aluminium catalysts.

Entry Catalyst Loading/mol% Time/hr Temp/°C Conversiona/% Product distributionb/%
A B C D
1 3 5 5 20 72 25 5 27
2 3 5 44 20 78 35 5 23
3 3Si 5 16.5 20 17 5 1 11
4 3 1 2 20 28 8 1 <1 13
5 3 1 16.5 20 60 45 1 <1 14
6 1 5 24 20 0 0 0 0 0
7 1 5 24 60 31 11 15
a

Conversion of Me2NHBH3 based on 11B NMR integrals.

b

Ratio of products based on 11B NMR integrals.