Fe(TF₄DMAP)Cl-catalysed intramolecular C–H amination of N-containing alkyl azides under photocatalytic conditions^a.

Entry	Substrate	Product	Yield (%)
1			75
2			70
3			78
4			61; 30b
5			45
6			98
7			95
8			55

^aReactions were run under argon with 0.3 mmol of the azide, Boc₂O (0.36 mmol), 3 × 10⁻³ mmol of the catalyst (1 mol% with respect to the azide) and 120 mg 4 Å MS in 2.0 mL of anhydrous DCE in a 10.0 mL sealed tube. The tube was irradiated with a blue LED at 25–35 °C. Isolated yields are shown.

^b[Fe(F₂₀TPP)Cl] was used as the catalyst. Yields were determined by ¹H NMR spectroscopy.