Fe(TF₄DMAP)Cl-catalysed intramolecular C–H amination of α-azidoketones under photocatalytic conditions^a.

Entry	Substrate	Product	Conv. (%)	Yield (%)
1			70	46 (42)
2			100	90 (80)
3			100	92 (85)
4			100	82 (77)
5			100	84 (77)
6			100	90 (82)

^aReactions were run under argon with 0.3 mmol of the azide, Boc₂O (0.36 mmol), 9 × 10⁻³ mmol of the catalyst (3 mol% with respect to the azide) and 120 mg 4 Å MS in 2.0 mL of anhydrous DCE in a 10.0 mL sealed tube. The tube was irradiated with a blue LED at 25–35 °C. Isolated yields are shown in the brackets.