Binding energies of K for various combined concentrations of K and H2O occupying the two tunnels of α-Mn8O16. [K] and [H2O] indicate the total K+ and H2O concentrations summed over the two tunnels of hollandite.
[K] | [H2O] | [BEK (eV)] |
---|---|---|
0.80 | 1.40 | −3.621 |
1.05 | 0.65 | −4.689 |
1.05 | 0.90 | −4.301 |
1.05 | 1.15 | −4.059 |
1.13 | 0.73 | −4.443 |
1.13 | 1.07 | −3.987 |
1.30 | 0.65 | −4.256 |
1.30 | 0.90 | −4.361 |
1.47 | 0.73 | −4.049 |
1.55 | 0.65 | −4.089 |