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. 2020 Apr 22;11(25):6485–6491. doi: 10.1039/d0sc01291b

Polymerization of racemic lactide with cationic alkyl indium complexesa.

graphic file with name d0sc01291b-u6.jpg
Catalyst Conv.b (%) M n Cal c (Da) M n d (Da) Đ e i*f (%)
1 2a <1
2 2b 20
3 2c 94 34 000 130 000 1.32 26
a

Reactions were performed for 24 h in toluene at 100 °C. [rac-LA] = 1.6 M, [cat] = 6.4 mM. [rac-LA]/[cat] = 250.

b

Conversion was monitored by 1H NMR spectroscopy.

c

M n Cal = calculated number averaged molecular weight = [rac-LA]/[cat] × conversion × molar mass of rac-LA.

d

M n determined through GPC in THF.

e

Dispersity = Mw/Mn.

f

Initiation efficiency = (Mn Cal/Mn) × 100.