Polymerization of racemic lactide with cationic alkyl indium complexesa.
| ||||||
|---|---|---|---|---|---|---|
| Catalyst | Conv.b (%) | M n Cal c (Da) | M n d (Da) | Đ e | i*f (%) | |
| 1 | 2a | <1 | — | — | — | — |
| 2 | 2b | 20 | — | — | — | — |
| 3 | 2c | 94 | 34 000 | 130 000 | 1.32 | 26 |
Reactions were performed for 24 h in toluene at 100 °C. [rac-LA] = 1.6 M, [cat] = 6.4 mM. [rac-LA]/[cat] = 250.
Conversion was monitored by 1H NMR spectroscopy.
M n Cal = calculated number averaged molecular weight = [rac-LA]/[cat] × conversion × molar mass of rac-LA.
M n determined through GPC in THF.
Dispersity = Mw/Mn.
Initiation efficiency = (Mn Cal/Mn) × 100.