Allylic carbonate substrate scope^a,b,c.

^aReaction conditions: Mo(CO)₆ (10 mol%), L1 (15 mol%), 1 (0.2 mmol), PhSO₂Na 2a (0.3 mmol), EtOH (1.0 mL, 0.2 M), 60 °C, 24 hours.

^bRegioselectivity was determined by ¹H-NMR of the crude reaction mixture.

^cIsolated yields of the products.