Tensile properties of the block polyester elastomers TBPE-6 to -9a.
Sample | ε b b (%) | σ b c (MPa) | E y d (MPa) | G′e (MPa) | M e f (kg mol−1) |
---|---|---|---|---|---|
TBPE-6 | 1097 ± 37 | 6.5 ± 0.2 | 5.0 ± 0.7 | 2.4 | 2.9 |
TBPE-7 | 1437 ± 30 | 5.6 ± 0.3 | 3.6 ± 0.5 | 1.1 | 5.5 |
TBPE-8 | 1593 ± 41 | 4.0 ± 0.2 | 2.4 ± 0.4 | 0.5 | 9.0 |
TBPE-9 | 1883 ± 20 | 2.0 ± 0.2 | 1.4 ± 0.3 | 0.4 | 9.1 |
Samples were tested at 10 mm min−1 extension rate, GL = 10 mm, width measured as an average of 3; error represents standard deviation of 10 specimens.
Elongation at break.
Tensile strength.
Young's modulus measured within 0.025–0.25% strain using an external camera.
Shear storage modulus at 25 °C calculated from the plateau storage modulus (E′), as illustrated in Fig. 1B and applying E′ = 2G′(1 + ν) where Poisson's ratio, ν = 0.5 which is typical of elastomers.83
Calculated using the Guth–Smallwood equation at 25 °C: Me = ρRT(1 + 2.5fhard + 14.1fhard2)/G′ using ρPDL = 0.974 g cm−3.21