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. 2020 Jun 1;11(23):5974–5986. doi: 10.1039/d0sc02611e

Compositions of bottlebrush copolymers.

Entry Copolymer N (PLA 6.6 k) a N (PEO 3 kDa) b N (PNIPAM 5.5 k) b M n (kg mol−1)b Đ
AB PLA-b-PEG 7.6 43.2 179 1.12
ABC PLA-b-PEG-b-PNIPAM 7.6 43.8 8.6 229 1.25
CBA PNIPAM-b-PEG-b-PLA 7.6a 40a 10a 225 1.35
ABC-stat PLA-co-PEG-co-PNIPAM 7.6 41.4 8.2 219 1.21
a

Assumed quantitative incorporation based on SEC analysis.

b

Based on 1H NMR peak integrations relative to PLA content.