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. 2020 Apr 15;11(29):7634–7640. doi: 10.1039/d0sc01229g

Substrate scope for the oxidative transformation of aryl alcohols to thioethersa.

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Substrates Products Yield Substrates Products Yield
graphic file with name d0sc01229g-u3.jpg graphic file with name d0sc01229g-u4.jpg 97% graphic file with name d0sc01229g-u5.jpg graphic file with name d0sc01229g-u6.jpg 79%*
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a

Experiments were performed on the 0.2 mmol scale unless otherwise noted. Optimized conditions: 0.2 mmol alcohols, 0.4 mmol diphenyldisulfane, 0.08 mmol CuSO4, 0.04 mmol phen, 0.8 mmol K2CO3, 200 mg 4 Å, 2 mL DMSO, 0.5 MPa O2, 140 °C, 12 h. *24 h. Yield was determined by GC.