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. 2020 Apr 7;11(17):4381–4390. doi: 10.1039/d0sc01026j

Results of the transfer-hydrogenation of 2-phenylquinoline with catalysts 1a/b/c and 2a/b/c.

graphic file with name d0sc01026j-u1.jpg
Catalysta eeb [%] v 0 [10−7 M s−1] Catalysta eeb [%]
(S,S)-1a 81 3.7 (S)-2a −17
(S,S)-1b 84 3.1 (S)-2b −12
(S,S)-1c 82 2.0 (S)-2c −17
a

2.5 mol% catalyst, 5 mM quinoline.

b

Determined by chiral HPLC. Values given for the excess of (R)-6.