Table 6.
Titration data and statistics for (a) Hyamine 1622, (b) CPC, (c) CTAB and (d) DMIC titration with SDS (c = 4 mM) using DMI-TPB sensors prepared with six different plasticisers (P1–P6). ΔE, mV is the difference between the end and the start potential; dE/dV is the value of first derivative in the end-point. The statistics were based on five independent measurements.
DMI-TPB Sensor Plasticizer Type | |||||||
---|---|---|---|---|---|---|---|
P1 | P2 | P3 | P4 | P5 | P6 | ||
Hyamine 1622 with SDS | ΔE, mV | 290.1 | 263.4 | 278.2 | 248.6 | 252.4 | -/- |
dE/dV | 61.5 | 59.1 | 43:5 | 43.1 | 55.3 | -/- | |
SDS consumption in EP, mL | 4.83 | 4.83 | 4.79 | 5.07 | 4.79 | -/- | |
SD of EP | 0.013 | 0.023 | 0.018 | 0.054 | 0.018 | -/- | |
CPC with SDS | ΔE, mV | 321.7 | 314.9 | 304.0 | 263.8 | 313.3 | 39.4 |
dE/dV | 69.4 | 67.7 | 46.4 | 45.0 | 62.2 | 9.6 | |
SDS consumption in EP, mL | 4.78 | 4.76 | 4.69 | 4.79 | 4.72 | 4.86 | |
SD | 0.016 | 0.018 | 0.016 | 0.059 | 0.019 | 0.035 | |
CTAB with SDS | ΔE, mV | 325.7 | 294.7 | 276.2 | 260.2 | 286.1 | 11.6 |
dE/dV | 71.5 | 67.9 | 54.8 | 56.9 | 65.2 | 13.9 | |
SDS consumption in EP, mL | 4.97 | 4.92 | 4.92 | 4.91 | 4.94 | 4.96 | |
SD | 0.024 | 0.015 | 0.037 | 0.035 | 0.038 | 0.027 | |
DMIC with SDS | ΔE, mV | 357.6 | 325.2 | 300.3 | 292.5 | 303.2 | 54.6 |
dE/dV | 66.6 | 61.4 | 52.4 | 46.2 | 59.1 | 33.8 | |
SDS consumption in EP, mL | 4.73 | 4.70 | 4.69 | 4.75 | 4.71 | 4.96 | |
SD | 0.027 | 0.015 | 0.014 | 0.026 | 0.015 | 0.025 |