Hydrogenation of fluorinated allylic acetates^a.

^aReaction conditions: 0.25 mmol of substrate, 1 mol% catalyst, 2.0 mL CH₂Cl₂.

^bCatalyst F.

^cCatalyst ent-F. Yields are isolated hydrogenated product. Enantiomeric excess was determined by SFC or GC/MS using chiral stationary phases.