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. 2020 Apr 27;11(39):10786–10791. doi: 10.1039/d0sc01445a

Summary of the influence of key reaction parametersa.

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Entry Ligand Anode Cathode Solvent Yield (%)
1 L1 FTO Carbon fibre THF/CH3CN = 4 : 1 56
2 L1 FTO Carbon fibre THF/CH3CN = 4 : 1 76b
3 L2 FTO Carbon fibre THF/CH3CN = 4 : 1 43
4 L3 FTO Carbon fibre THF/CH3CN = 4 : 1 46
5 L4 FTO Carbon fibre THF/CH3CN = 4 : 1 21
6 L1 FTO Carbon fibre CH3CN 4
7 L1 FTO Carbon fibre DMA 15
8 L1 FTO Carbon fibre DMF 6
9 L1 FTO Ni foam THF/CH3CN = 4 : 1 45
10 L1 FTO Pt foil THF/CH3CN = 4 : 1 28
11 L1 Carbon fibre (1 cm2) Carbon fibre THF/CH3CN = 4 : 1 0
12 L1 Pt foil (cm2) Carbon fibre THF/CH3CN = 4 : 1 7
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a

Reaction conditions: 1a (0.6 mmol), 2a (0.2 mmol), (DME)NiBr2 (6 mol%), ligand (7.2 mol mol%), LutHClO4 (0.1 M), and lutidine (0.8 mmol) in solvent (2 mL) at 40 °C. GC yield.

b

Reaction time: 36 h. Isolated yield.