Fig. 8. Ligand field multiplet calculations of the Fe L3-edge as a function of Dq splitting, normalised through second peak intensity. The Dt and Ds crystal field and spin–orbit coupling parameters are fixed to the optimised vales used in Fig. 6a. (Black) Experimental spectrum of Li2(Li0.985Fe0.015)N. (Inlay) Energy separation, ΔE of MJ ±7/2 and ±5/2 states with respect to Dq.
