The photophysical properties of probes 1–34.
| Probe | Solvent | Max λex/nm | Max λem/nm | ε a/M−1 cm−1 | Φ b | K d c | LODd | ||||
|---|---|---|---|---|---|---|---|---|---|---|---|
| No Zn2+ | With Zn2+ | No Zn2+ | With Zn2+ | No Zn2+ | With Zn2+ | No Zn2+ | With Zn2+ | ||||
| 1 | HEPES buffer | 470 | 470 | 517 | 517 | NRe | NR | <0.005 | 0.18 | 126 nM | NR |
| 2 | PIPES buffer | 643 | 637 | 663 | 662 | 3.68 × 104 | 3.62 × 104 | 0.038 | 0.21 | 4 pM | NR |
| 3 | HEPES buffer | 493 | 493 | 515 | 515 | 7.3 × 104 | NR | 0.0032 | 0.225 | 0.45 μM | NR |
| 4 | HEPES buffer | 347 | 347 | 420 | 443 | NR | NR | NR | NR | NR | NR |
| 5 | MOPS/DPPC (1 : 1) | 400 | 415 | 506 | 520 | 1.64 × 104 | NR | 0.19 | NR | 20 ± 0.4 nM | NR |
| 6 | MOPS buffer | 545 | NR | 575 | 575 | NR | NR | NR | NR | 65 ± 10 nM | NR |
| 7 | PIPES buffer | 497 | 490 | 522 | 517 | 3.3 × 104 | 4.2 × 104 | 0.36 | 0.80 | 1.5 ± 0.2 μM | NR |
| 8 | PIPES buffer | 569 | 573 | 629 | 631 | 2.84× 104 | 3.67 × 104 | 0.0355 | 0.5025 | 3.25 ± 0.12 nM | NR |
| 9 | MOPS buffer | 388 | 375 | 500 | 493 | 1.87 × 104 | 2.31 × 104 | 0.15 | 0.92 | 3.1 nM | NR |
| 10 | HEPES buffer | 413 | 395 | 536 | 536 | 1.85 × 104 | 2.10 × 104 | 0.0048 | 0.33 | 1.4 nM | NR |
| 11 | MOPS buffer | 392 | NR | 559 | NR | 1.32 × 104 | NR | 0.023 | NR | 17 ± 2 nM | NR |
| 12 | HEPES buffer | 453 | 391 | 625f | 542f | 6.2 × 103 | 4.2 × 103 | NR | 0.03 | 8.2 ± 0.2 nM | NR |
| 13 | HEPES buffer | 420 | 370 | 550 | 504 | NR | NR | 0.11 | 0.22 | 0.45 ± 0.01 nM | NR |
| 14 | CH3CN | 347g | 363g | 633 | 633 | 81 × 103g | 67 × 103g | 0.28i | 0.29j | 9.1 μM | NR |
| 602h | 602h | 23 × 103h | 21 × 103h | ||||||||
| 15 | PIPES buffer | 510 | 510 | 535 | 529 | NR | NR | <0.001 | 0.75 ± 0.03 | 0.6 ± 0.03 nM | NR |
| 16 | HEPES buffer | 496 | 469 | 550 | 534 | 2.10 × 104 | 1.40 × 104 | 0.003 | 0.046 | 1.0 ± 0.1 nM | NR |
| 17 k | MES buffer | 285 | 261 | 542 | 495 | 4.30 × 103 | 1.66 × 103 | 0.11 | 0.17 | 16 ± 1.1 nM | NR |
| 18 l | MES buffer | 435 | 444 | 528 | 536 | 1.55 × 104 | 1.81 × 104 | 0.03 | 0.23 | 8.5 μM | 0.18 μM |
| 19 | EtOH/Tris–HCl (9 : 1) | 597 | 568 | 647 | 578 | NR | NR | NR | 0.23 | 68 ± 4 μMm | 0.48 μM |
| 123 ± 6 μMn | |||||||||||
| 20 | MES buffero | 500 | 490 | 536 | 536 | NR | NR | NR | NR | NR | 0.477 μM |
| 21a | HEPES buffer/CH3CN (1 : 1) | 350 | 365 | 504 | 504 | NR | NR | 0.25 | 0.24 | 1 nM2 | NR |
| 21b | 350 | 359 | 504 | 504 | NR | NR | 0.32 | 0.33 | 0.17 nM2 | NR | |
| 22a | HEPES buffer | 456 | 454 | 515 | 515 | NR | NR | 0.0027 | 0.0482 | 1.54 nM | NR |
| 22b | HEPES buffer | 454 | 451 | 509 | 515 | NR | NR | 0.0064 | 0.2606 | 2.57 nM | NR |
| 22c | HEPES buffer | 453 | 453 | 512 | 517 | NR | NR | 0.0077 | 0.3283 | 1.91 nM | NR |
| 23a | PIPES buffer | 478 | 530 | 625 | 628 | 1.93 × 104 | 2.64 × 104 | 0.067 | 0.41 | 0.69 nM | NR |
| 23b | PIPES buffer | 480 | 524 | 630 | 630 | 1.69 × 104 | 2.56 × 104 | 0.069 | 0.22 | 0.70 nM | NR |
| 23c | PIPES buffer | 480 | 535 | 623 | 628 | 1.33 × 104 | 1.93 × 104 | 0.342 | 0.60 | <0.001 nM | NR |
| 24 | EtOH | 406 | NR | 490 | NR | NR | NR | <0.01 | 0.12 | 5.5 nM | 5.8 nM |
| 25 | HEPES buffer | 346 | 346 | 414 | 414 | NR | NR | 0.041 | 0.25 | 3.5 nM | 47 pM |
| 26 | HEPES buffer | 346 | 346 | 414 | 414 | NR | NR | 0.013 | 0.041 | 4.7 nM | 0.71 nM |
| 27 | HEPES buffer | 346 | 346 | 414 | 414 | NR | NR | 0.05 | 0.28 | 2.83 ± 0.11 nM | 48 pM |
| 28 | PIPES buffer | 515 | 507 | 530 | 525 | 7.95 × 104 | 8.40 × 104 | 0.39 | 0.87 | 0.7 ± 0.1 nM | NR |
| 29a | PIPES buffer | 499 | 496 | 519 | 514 | 2.72 × 104 | 1.60 × 104 | 0.004 | 0.73 | p | NR |
| 29b | PIPES buffer | 498 | 492 | 515 | 515 | 6.41 × 104 | 4.00 × 104 | 0.012 | 0.51 | q | NR |
| 30 | HEPES buffer | 302 | 360 | 532 | 532 | 420 | 4680 | 0.015 | 0.055 | 1.8 ± 0.1 pM | 0.042 pM |
| 32a | MOPS buffer | 384 | 388 | 518 | 518 | 2.89 × 104 | NR | 0.12l | 0.93l | 1.7 nMr | NR |
| 33 | HEPES buffer | 453 | 442 | 546 | 536 | NR | NR | NR | 0.19 | 4 nM | 57 nM |
| 34 | HEPES buffer | 346 | 346 | 414 | 414 | NR | NR | 0.02 | 0.05 | 18.8 nM | NR |
Molar extinction coefficient.
Fluorescence quantum yield.
Dissociation constant.
The limit of detection.
Not reported.
λ ex = 466 nm.
The parameters of donor.
The parameters of acceptor.
λ ex = 565 nm.
λ ex = 400 nm.
All results shown here were recorded at lysosomal pH 5.2.
All results shown here were recorded at lysosomal pH 5.0.
Calculated from turn on fluorescence emission at wavelength 578 nm.
Calculated from the ratio of F578 nm/F680 nm.
The pH of the buffer is 5.0.
K d1 = 3.5 ± 0.1 mM, Kd2 = 150 ± 100 μM.
K d1 = 220 ± 30 μM, Kd2 = 160 ± 80 μM, Kd3 = 9 ± 6 μM.
The results were obtained in solution EtOH : MOPS buffer (1 : 1, v/v).