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. 2020 Jul 1;11(30):7864–7870. doi: 10.1039/d0sc02718a

Catalytic activity of the GaN NW with different doping and sacrificial reagents.

graphic file with name d0sc02718a-u1.jpg
Entry GaN NW Sacrificial reagent Yield/% Rac- : meso-
1 i-GaN MeOH 93 1 : 1
2 n-GaN MeOH 81 1 : 1
3 p-GaN MeOH >99 1 : 1
4 p-GaN H2 No reaction N/A
5 p-GaN CH4 No reaction N/A
6 p-GaN Water No reaction N/A
7 p-GaN Et3N >99 1 : 1
8 p-GaN EtOH >99 1 : 1
9 p-GaN Triethanolamine 92 1 : 1
10 p-GaN MeOH (no GaN) No reaction N/A
11 p-GaN MeOH (in dark) No reaction N/A
12 Si(111) MeOH No reaction N/A
13 p-GaN (no Si) MeOH 97 1 : 1
a

Reaction was done by injecting all reactants into a sealed quartz vessel under vacuum. NMR yields were determined by using mesitylene as the internal standard.