Catalytic activity of the GaN NW with different doping and sacrificial reagents.
| ||||
|---|---|---|---|---|
| Entry | GaN NW | Sacrificial reagent | Yield/% | Rac- : meso- |
| 1 | i-GaN | MeOH | 93 | 1 : 1 |
| 2 | n-GaN | MeOH | 81 | 1 : 1 |
| 3 | p-GaN | MeOH | >99 | 1 : 1 |
| 4 | p-GaN | H2 | No reaction | N/A |
| 5 | p-GaN | CH4 | No reaction | N/A |
| 6 | p-GaN | Water | No reaction | N/A |
| 7 | p-GaN | Et3N | >99 | 1 : 1 |
| 8 | p-GaN | EtOH | >99 | 1 : 1 |
| 9 | p-GaN | Triethanolamine | 92 | 1 : 1 |
| 10 | p-GaN | MeOH (no GaN) | No reaction | N/A |
| 11 | p-GaN | MeOH (in dark) | No reaction | N/A |
| 12 | Si(111) | MeOH | No reaction | N/A |
| 13 | p-GaN (no Si) | MeOH | 97 | 1 : 1 |
Reaction was done by injecting all reactants into a sealed quartz vessel under vacuum. NMR yields were determined by using mesitylene as the internal standard.