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. Author manuscript; available in PMC: 2021 Aug 12.
Published in final edited form as: J Am Chem Soc. 2020 Jul 29;142(32):13779–13794. doi: 10.1021/jacs.0c04226

Figure 3.

Figure 3.

EPR spectra of the CuA-like species (top) and the green T2Cu intermediate (bottom) at pH 7.4. Spectra have been normalized to their minima. Experimental data are drawn as black lines, and simulated spectra as red lines. Samples were measured at 2 mW power, 9.17 GHz (top) and 9.29 GHz (bottom) at a temperature of 77 K; a similar spectrum for the CuA-like species was obtained at 30 K.