Skip to main content
. Author manuscript; available in PMC: 2021 Aug 12.
Published in final edited form as: J Am Chem Soc. 2020 Jul 29;142(32):13779–13794. doi: 10.1021/jacs.0c04226

Table 4.

Rate Constants Calculated from Global Spectral Fitting of the Stopped-Flow Spectra of Cu Incorporation in CuACcP

Process Rate (s−1) St. Dev. (s−1)
Apo + Cu(II) → IT2 kl 6.86 × 104 0.072 × 104
2 IT2 → A(S•SH) + CuA k2 1.03 × 102 0.0071 × 102
A(S•SH) + Cu(II) → Cu(I) + A(S–S) k3 3.40 × 102 0.25 × 102
IT2 + Cu(I) → CuA k4 1.76 × 102 0.078 × 102