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. 2021 Jun 1;12:3264. doi: 10.1038/s41467-021-23582-2

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© The Author(s) 2021

Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.

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Fig. 4 — a The logarithms of partial current densities for CH₄ formation plotted in RHE scale. b The change of Tafel slope for CH₄ formation at less biased potentials in electrolyte with pH 9.0. c, d Possible RDS shift of CH₄ formation by decreasing overpotential. The error bars represent SD from at least three independent measurements.