Table 1. Optimized Kinetic Parameters for the Component Reaction Steps of the Thermal Dehydration of Included Water in FW-Pearl, Averaged Over Different β Values (Determination Coefficient R2 = 0.9971 ± 0.001).
|
fi (αi) = αimi (1 – αi)ni[−ln(1 – αi)]pi |
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|---|---|---|---|---|---|---|
| i | ci | Ea,i/kJ mol–1 | Ai/s–1 | mi | ni | pi |
| 1 | 0.14 ± 0.01 | 160.4 ± 0.8 | (1.28 ± 0.03) × 1016 | 1.53 ± 0.02 | 8.29 ± 0.43 | –1.84 ± 0.03 |
| 2 | 0.73 ± 0.04 | 193.6 ± 0.5 | (5.85 ± 0.03) × 1014 | 5.67 ± 0.70 | 0.47 ± 0.02 | –6.40 ± 0.64 |
| 3 | 0.13 ± 0.04 | 219.6 ± 1.2 | (1.66 ± 0.01) × 1013 | –2.54 ± 0.26 | 1.09 ± 0.13 | 0.88 ± 0.06 |