Table 2. Catalytic Oxidation of Sugars with H₂O₂ and FePcS Catalyst at 50 °C.

									yield (mol %)
no.	substrate	substrate (mM)	FePcS (μM)	H2O2 (mol equiv)	time (h)	pH before	pH after	conversion (mol %)	FRU	FA
1	d-glucose	49	0	0	16	10.7	10.2	15	14	nda
2	d-glucose	49	0	–b	16	10.2	9.8	9	3	3
3	d-glucose	47	28	1	16	10.6	9.9	39	20	32
4	d-glucose	47	28	2	16	10.5	9.8	33	16	34
5	d-glucose	46	27	3	16	10.9	9.8	35	14	55
6	d-glucose	46	37	1	23	9.5	9.1	19	6	11
7	d-glucose	47	35	1	23	10.5	9.9	53	21	44
8	d-glucose	48	77	2	16	10.4	9.7	32	15	31
9	d-glucose	47	115	2	16	10.6	9.7	36	17	38
10	d-glucose	48	154	2	16	10.5	9.8	34	17	29
11	α-MGP	44	36	1	23	10.5	10.5	2	nd	nd
12	d-sorbitol	46	36	1	23	10.5	10.3	4	nd	16
13	d-cellobiose	47	35	1	23	10.5	9.7	49	46c	55
14	d-cellobiose	46	27	1	23	10.5	9.7	47	25c	34
15	d-cellobiose	46	27	2	23	10.5	9.6	42	31c	29
16	d-cellobiose	46	27	3	23	10.6	9.6	40	37c	61

^and means not detected in HPLC.

^b1.76 μM H₂O₂.

^cTotal yield of d-glucose and isomerization products.