Variation of the reaction conditions^a.

Entry	Variation of reaction conditions	Yield B1b (%)
1	None (standard)	95
2	[Ir(dF(CF3)ppy)2(dtbbpy)](PF6) instead of 3DPAFIPN	52
3	C6F5Br instead of C6F5I	N. D.
4	CH3CN instead of CH2Cl2	3
5	THF instead of CH2Cl2	12
6	1,2-DCE instead of CH2Cl2	91
7	K3PO4 instead of K2CO3	4
8	Triethylamine instead of K2CO3	N. D.
9	18 h reaction time	49
10	No 3DPAFIPN	4
11	No C6F5I	N. D.
12	No K2CO3	32
13	Dark condition	N. D.

^aReaction conditions: A1 (0.2 mmol), 3DPAFIPN (0.012 mmol), C₆F₅I (0.8 mmol), K₂CO₃ (0.6 mmol), CH₂Cl₂ (1 mL) in a 4 mL reaction vial, irradiated with a 34 W Kessil blue LED for 24 h under fan cooling.

^bDetermined by GC using dodecane as an internal standard. THF = tetrahydrofuran. N. D. = not detected.