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. 2020 Dec 7;12(5):1750–1755. doi: 10.1039/d0sc02940h

ECCD of chiral bis-phosphine oxides bound to Zn-MAPOL 2.

Entry Predicted sign λ nm, Δε A/Acorra
graphic file with name d0sc02940h-u10.jpg Positive 427, +416 +612
418, −196
graphic file with name d0sc02940h-u11.jpg Negative 427, −426 −654
418, +228
graphic file with name d0sc02940h-u12.jpg Negative 429, −1838 −3460
420, +1622
graphic file with name d0sc02940h-u13.jpg Positive 429, +332 +586
421, −254
graphic file with name d0sc02940h-u14.jpg Negative 427, −1646 −2770
419, +1124
graphic file with name d0sc02940h-u15.jpg Positive 427, +1862 +3110
419, −1248
graphic file with name d0sc02940h-u16.jpg Negative 427, −1350 −2154
418, +804
a

A corresponds to the amplitude for the ECCD spectrum, measured with the addition of 1 equiv. of the bis-phosphine oxide to a 1 μM Zn-MAPOL 2 solution.