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. 2020 Dec 15;12(7):2433–2440. doi: 10.1039/d0sc06210c

Cathodic shift ΔE (mV) of 1.XB/HB and 2.XB/HBSAM in ACN or ACN/H2O 99 : 1 in the presence of 50 mM of various anions unless otherwise stated. N.r. – no response. — – not carried out. Estimated error ± 5 mV.

ACN ACN/H2O 99 : 1
1.XB 1.HB 1.XB 1.HB 2.XBSAM 2.HBSAM
Cl −79 −37 −63 −44 −118 −114
Br −57 −45 −57 −32 −34a −31a
HSO4 −65 −51 −62 −53 −96 −106
H2PO4 −173b −109b −147 −59b −158b −175b
NO3 −35 N.r. −36 N.r. −43 −45
OBz −106 −62 −78 N.r.
a

ΔE at ≈2 mM, response not plateauing.

b

ΔE at <50 mM, response at plateau.