Cathodic shift ΔE (mV) of 1.XB/HB and 2.XB/HBSAM in ACN or ACN/H2O 99 : 1 in the presence of 50 mM of various anions unless otherwise stated. N.r. – no response. — – not carried out. Estimated error ± 5 mV.
ACN | ACN/H2O 99 : 1 | |||||
---|---|---|---|---|---|---|
1.XB | 1.HB | 1.XB | 1.HB | 2.XBSAM | 2.HBSAM | |
Cl− | −79 | −37 | −63 | −44 | −118 | −114 |
Br− | −57 | −45 | −57 | −32 | −34a | −31a |
HSO4− | −65 | −51 | −62 | −53 | −96 | −106 |
H2PO4− | −173b | −109b | −147 | −59b | −158b | −175b |
NO3− | −35 | N.r. | −36 | N.r. | −43 | −45 |
OBz− | −106 | −62 | −78 | N.r. | — | — |
ΔE at ≈2 mM, response not plateauing.
ΔE at <50 mM, response at plateau.