Chiroptical data of 1a and 1b.

Compound	[α]25Dd	[M]25De	g abs f/10−3 (wavelength)	g lum g/10−3 (wavelength)
(Sp,Sp)-(M,M,M,M)-1a (>99% ee)a	−3357°	−45 700°	−9.48 (461)	−4.92 (512)
(Rp,Rp)-(P,P,P,P)-1a (>99% ee)b	—	—	+9.58 (462)	+4.95 (512)
(Sp,Sp,Rp)-(M,M,M,M,P,P)-1b (62% ee)a	−466°c	−9520°c	−2.74 (422)c	−1.67 (490)c
(Rp,Rp,Sp)-(P,P,P,P,M,M)-1b (62% ee)b	—	—	+2.90 (424)c	+1.97 (488)c

^aIn CH₂Cl₂ (1.0 × 10⁻⁵ M) at 25 °C.

^bIn CH₂Cl₂ (1.1 × 10⁻⁵ M) at 25 °C.

^cValues are calculated as 100% ee.

^d[α]²⁵_D: optical rotation.

^e[M]²⁵_D: molar optical rotation (= M[α]²⁵_D/100).

^f g _abs: CD dissymmetry factor.

^g g _lum: CPL dissymmetry factor.