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. 2021 May 11;12(22):7623–7655. doi: 10.1039/d0sc06894b

Comparison of the typical features of different KIB anodes.

Type Advantages Disadvantages
Alloying-type anode High potassium storage capability Huge volume change; side reactions; poor cycling stability
Intercalation-type compound Enhanced initial coulombic efficiency; impressive working stability Low specific capacity; high working voltage
Conversion-type anode Good specific capacity; facile synthesis process Unstable structural re-alignment; large voltage hysteresis
Compound anodes with multiple potassium storage behaviors Diverse chemical sources; rationally designed potassium storage Synthesis process is relatively difficult; complicated reaction behavior
Carbonaceous anodes For disordered carbonaceous anode: prolonged cycling stability For disordered carbonaceous anode: enhanced average operation voltage; low coulombic efficiency
For graphite: low cost; direct utilization without further treatment For graphite: voltage polarization; low rate performances
Organic anodes Good processability; a wide range of sources Solubility in organic electrolyte; low energy density; inferior electronic conductivity