Fig. 3. TEM images and syn-SAXS analysis of the core-shell configurations of BPI/BPII/BPIII, BPI/BPIII, and BPII/BPIII.
a1 Textures observed in reflection mode using cross-polarized microscopy. The yellow circle highlights the monophase or interface in core-shell configurations. The inserts in a1, b2, and c2 are schematic illustrations of the arrangements of cubic cells at the interfaces of BPIII, BPII, and BPI or monophasic BPII and BPI. a2, a3 TEM images of the interface between BPI{110} and BPII{100}, b1, b2 the interface between BPI{110} and BPIII, and c1, c2 the interface between BPII{100} and BPIII. a4 Syn-SAXS patterns with background subtracted from a monodomain a4 hybrid phase of BPI{110} and BPII{100}. “BPII/I” refers to hybrid phases of BPII and BPI. The crystal lattices of BPI and BPII are coherent and a DTC can simultaneously exist in both BPI and BPII units, confirming that the DTC undergoes a reconfiguration process without diffusion. In addition, a DTC is observed across the interface of BPIII/BPI or BPIII/BPII, indicating that the DTCs do not diffuse when phase transition occurs from BPIII to BPII or BPI. The interfaces of BPI/BPII, BPII/BPIII, and BPI/BPIII are clear without a nearby transitional region. Based on the syn-SAXS results in reciprocal-space, the crystal orientation relationship between BPI and BPII is confirmed as {211}BPI//{110}BPII. Moreover, a perfect monodomain BPI with a large size is characterized.