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. 2021 May 24;6(22):14174–14181. doi: 10.1021/acsomega.1c00765

Table 2. Fitting Parameters of the Fluorescence Anisotropy Decay Dynamics and the Radius Estimated by Different Methods.

    C-dotsMW C-dotssonicatedMW C-dots100°CMW C-dots200°CMW
fluorescence anisotropya τ1 (a1) 0.32 ns(0.16) 1.57 ns (0.25) 0.31 ns (0.17)  
  τ2 (a2) 1.82 ns (0.10) 22.5 ns (0.06) 1.91 ns (0.06) 0.20 ns (0.22)
  τs 0.39 ns 1.68 ns 0.37 ns  
hydrodynamic radius estimated by τ2b   1.3 nm 2.9 nm 1.3 nm 0.7 nm
radius estimated by TEM   1.2 nm 1.5 nm 1.0 nm 0.9 nm
a

Fluorescence anisotropy, r(t) = a1 × e–t/τ1 + a2 × e–t/τ2.

b

T = 298 K and η = 0.89 cP.