Table 2. Fitting Parameters of the Fluorescence Anisotropy Decay Dynamics and the Radius Estimated by Different Methods.
C-dotsMW | C-dotssonicatedMW | C-dots100°CMW | C-dots200°CMW | ||
---|---|---|---|---|---|
fluorescence anisotropya | τ1 (a1) | 0.32 ns(0.16) | 1.57 ns (0.25) | 0.31 ns (0.17) | |
τ2 (a2) | 1.82 ns (0.10) | 22.5 ns (0.06) | 1.91 ns (0.06) | 0.20 ns (0.22) | |
τs | 0.39 ns | 1.68 ns | 0.37 ns | ||
hydrodynamic radius estimated by τ2b | 1.3 nm | 2.9 nm | 1.3 nm | 0.7 nm | |
radius estimated by TEM | 1.2 nm | 1.5 nm | 1.0 nm | 0.9 nm |
Fluorescence anisotropy, r(t) = a1 × e–t/τ1 + a2 × e–t/τ2.
T = 298 K and η = 0.89 cP.