Table 3. k_a-Values Estimated from k_E1 and k_E2 in EA, with or without Fulfillment of the Requirements to Dimensionless Numbers as Indicators for PFO or PSO Kinetics^a.

		PFO kinetics: N1 < 0.2		PFO kinetics: N2 < 0.2		PFO kinetics: NOD,0 > 8 PSO kinetics: NOD,0 < 0.02
system no.	ka × 109 from IRA	N1	ka × 109	N2	ka × 109	NOD,0	*ka,1 × 109	**ka,2 × 109
1a	182	0.96	8460	0.01	203	146.5	205	37 450
1b	181	0.98	6630	0.01	199	76.9	202	22 200
1c	185	0.94	5407	0.01	195	54.8	198	14 900
2a	18.4	0.93	58.3	0.25	18.0	3.4	22.8	43.2
2b	16.6	0.95	31.9	0.38	13.8	1.9	20.0	68.8
2c	15.4	0.87	20.5	0.58	14.0	0.98	26.2	43.2
3a	5.97	0.97	42.35	0.11	5.95	8.25	6.65	71.8
3b	5.93	0.97	34.7	0.14	5.85	6.4	6.73	56.7
3c	6.21	0.97	31.3	0.17	6.15	5.2	7.29	48.9
4a	334	0.37	375	0.55	481	3.6	403	2270
4b	390	0.32	441	0.51	569	5.2	442	4690
4c	440	0.23	515	0.41	649	8.9	493	9210

^a*k_a,1 and **k_a,2 values were calculated from k_E1 and k_E2, respectively.