Table 5.
C1,2,4-triazole (g/mL) |
PG | PGB1 | |||||
---|---|---|---|---|---|---|---|
298 | 303 | 308 | 298 | 303 | 308 | ||
qe,exp (mg/g) | 325 | 394 | 473 | 412 | 496 | 587 | |
3.6 × 10−4 | Lagergren model | ||||||
qe,calc (mg/g) | 346.29 | 415.91 | 491.95 | 428.82 | 511.76 | 600.94 | |
k1 (×103 min−1) | 2.19 | 3.01 | 3.31 | 3.83 | 3.92 | 4.14 | |
χ 2 | 1.738 | 2.263 | 1.119 | 1.119 | 1.682 | 1.103 | |
R 2 | 0.998 | 0.998 | 0.998 | 0.999 | 0.998 | 0.999 | |
Ho model | |||||||
qe,calc (mg/g) | 449.72 | 482.38 | 564.84 | 579.40 | 616.92 | 696.22 | |
k2 [×106 (g/mg⋅ min)] | 1.26 | 1.62 | 2.43 | 2.89 | 3.51 | 3.92 | |
χ 2 | 4.014 | 4.686 | 5.976 | 2.411 | 5.499 | 5.040 | |
R 2 | 0.997 | 0.997 | 0.997 | 0.998 | 0.997 | 0.998 | |
3.6 × 10−3 | qe,exp (mg/g) | 432 | 491 | 593 | 507 | 583 | 659 |
Lagergren model | |||||||
qe,calc (mg/g) | 473.63 | 523.96 | 622.21 | 531.87 | 606.53 | 679.53 | |
k1 (×103 min−1) | 3.10 | 3.52 | 4.01 | 4.13 | 4.27 | 4.87 | |
χ 2 | 1.456 | 1.446 | 1.569 | 1.312 | 1.852 | 1.786 | |
R 2 | 0.998 | 0.999 | 0.998 | 0.997 | 0.998 | 0.997 | |
Ho model | |||||||
qe,calc (mg/g) | 546.70 | 621.17 | 709.71 | 649.28 | 694.28 | 766.03 | |
k2 [×106 (g/mg⋅ min)] | 2.19 | 2.46 | 3.11 | 3.07 | 3.72 | 4.01 | |
χ 2 | 2.071 | 2.539 | 2.390 | 2.772 | 2.083 | 2.310 | |
R 2 | 0.997 | 0.996 | 0.997 | 0.995 | 0.997 | 0.996 | |
7 × 10−3 | qe,exp (mg/g) | 449 | 504 | 606 | 519 | 594 | 667 |
Lagergren model | |||||||
qe,calc (mg/g) | 463.71 | 527.91 | 622.32 | 533.86 | 621.43 | 681.07 | |
k1 (×103 min−1) | 3.42 | 3.96 | 4.43 | 4.60 | 4.90 | 5.10 | |
χ 2 | 1.722 | 1.949 | 1.654 | 1.034 | 1.326 | 1.764 | |
R 2 | 0.997 | 0.997 | 0.998 | 0.998 | 0.997 | 0.999 | |
Ho model | |||||||
qe,calc (mg/g) | 567.15 | 613.04 | 713.83 | 621.28 | 734.63 | 796.60 | |
k2 [×106 (g/mg min)] | 3.09 | 3.87 | 4.11 | 3.35 | 4.19 | 5.17 | |
χ 2 | 2.609 | 2.913 | 1.895 | 2.776 | 2.864 | 3.775 | |
R 2 | 0.996 | 0.997 | 0.996 | 0.997 | 0.997 | 0.998 | |
15 × 10−3 | qe,exp (mg/g) | 457 | 512 | 618 | 529 | 601 | 672 |
Lagergren model | |||||||
qe,calc (mg/g) | 483.63 | 532.96 | 644.21 | 544.25 | 627.05 | 694.28 | |
k1 (×103 min−1) | 3.67 | 4.67 | 4.81 | 4.92 | 5.14 | 5.48 | |
χ 2 | 1.466 | 1.343 | 1.691 | 1.144 | 1.671 | 1.024 | |
R 2 | 0.997 | 0.999 | 0.998 | 0.998 | 0.999 | 0.999 | |
Ho model | |||||||
qe,calc (mg/g) | 568.17 | 624.11 | 754.83 | 635.77 | 729.27 | 783.34 | |
k2 [×106 (g/mg min)] | 3.85 | 4.38 | 5.83 | 4.23 | 4.97 | 5.73 | |
χ 2 | 3.050 | 3.208 | 3.903 | 3.887 | 4.321 | 3.678 | |
R 2 | 0.996 | 0.997 | 0.996 | 0.998 | 0.997 | 0.997 |