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. 2021 Jun 2;26(11):3340. doi: 10.3390/molecules26113340

Table 2.

Adsorption kinetic parameters of CPX onto FZn (adsorbent doses: 1.6 g L−1, pH: 5 to 6; contact time: 60 min).

Initial Concentration
10 mg L−1 15 mg L−1 20 mg L−1 25 mg L−1 35 mg L−1 50 mg L−1 70 mg L−1
Experimental
qe (mg g−1)
5.64 8.51 11.86 14.76 18.36 26.50 37.68
Pseudo-First Order
qe (mg g−1) ------ 0.59 1.12 1.68 4.68 6.18 3.39
k1 (min−1) ------ 0.03 0.04 0.04 0.07 0.07 0.04
Δqe (%) ------ 93 91 89 74 77 91
R 2 ------ 0.969 0.999 0.990 0.989 0.928 0.889
Pseudo-Second Order
qe (mg g−1) 5.68 8.56 12.0 14.8 18.9 27.3 38.17
k2 (min−1) 0.19 0.15 0.09 0.07 0.03 0.02 0.28
Δqe (%) 0.59 0.54 1.56 0.24 2.8 2.8 1.28
R 2 0.999 1 1 0.999 1 0.999 0.999
Intraparticle Diffusion Model
kd 1 0.146 0.146 0.164 0.224 1.073 1.351 0.7947
C 1 4.756 7.537 10.68 12.94 12.56 18.52 32.45
R 2 0.981 0.979 0.999 0.942 0.988 0.931 0.9751
kd 2 0.022 0.033 −0.008 0.055 0.297 0.428 0.455
C 2 5.39 8.160 11.945 14.163 16.077 23.234 34.18
R 2 0.831 0.980 0.7913 0.999 0.9812 0.9583 0.993