Table 2.
Initial Concentration | |||||||
10 mg L−1 | 15 mg L−1 | 20 mg L−1 | 25 mg L−1 | 35 mg L−1 | 50 mg L−1 | 70 mg L−1 | |
Experimental qe (mg g−1) |
5.64 | 8.51 | 11.86 | 14.76 | 18.36 | 26.50 | 37.68 |
Pseudo-First Order | |||||||
qe (mg g−1) | ------ | 0.59 | 1.12 | 1.68 | 4.68 | 6.18 | 3.39 |
k1 (min−1) | ------ | 0.03 | 0.04 | 0.04 | 0.07 | 0.07 | 0.04 |
Δqe (%) | ------ | 93 | 91 | 89 | 74 | 77 | 91 |
R 2 | ------ | 0.969 | 0.999 | 0.990 | 0.989 | 0.928 | 0.889 |
Pseudo-Second Order | |||||||
qe (mg g−1) | 5.68 | 8.56 | 12.0 | 14.8 | 18.9 | 27.3 | 38.17 |
k2 (min−1) | 0.19 | 0.15 | 0.09 | 0.07 | 0.03 | 0.02 | 0.28 |
Δqe (%) | 0.59 | 0.54 | 1.56 | 0.24 | 2.8 | 2.8 | 1.28 |
R 2 | 0.999 | 1 | 1 | 0.999 | 1 | 0.999 | 0.999 |
Intraparticle Diffusion Model | |||||||
kd 1 | 0.146 | 0.146 | 0.164 | 0.224 | 1.073 | 1.351 | 0.7947 |
C 1 | 4.756 | 7.537 | 10.68 | 12.94 | 12.56 | 18.52 | 32.45 |
R 2 | 0.981 | 0.979 | 0.999 | 0.942 | 0.988 | 0.931 | 0.9751 |
kd 2 | 0.022 | 0.033 | −0.008 | 0.055 | 0.297 | 0.428 | 0.455 |
C 2 | 5.39 | 8.160 | 11.945 | 14.163 | 16.077 | 23.234 | 34.18 |
R 2 | 0.831 | 0.980 | 0.7913 | 0.999 | 0.9812 | 0.9583 | 0.993 |