. 2021 Jun 3;21(11):3856. doi: 10.3390/s21113856

Table 9.

Chronological order of optical sensors for carbamates detection.

Type of Carbamates	Method	Material	Range of Detection	LOD	Year	References
Carbaryl	SPR	SAM/mAbs	-	6.858 mM	2005	[258]
Carbaryl	SPR	mAbs	0.089–0.268 nM	0.248 nM	2007	[185]
Methomyl	Fluorescence	C[4]/SiO₂/CdTe	-	0.080 µM	2007	[256]
Carbofuran	LFIA	anti-carbofuran	0–128.000 µM	32.000 µM	2009	[257]
Trizophos	LFIA	anti-trizophos	0–32.000 µM	4.000 µM	2009	[257]
Bendiocarb	Colorimetric	idophenyl acetate-AChE	0–10.000 nM	0.001 µM	2009	[121]
Carbaryl	Colorimetric	idophenyl acetate-AChE	0–10.000 nM	10.000 nM	2009	[121]
Carbofuran	Colorimetric	indoxyl acetate-R-DmAChE	0.005–45.197 µM0.006–61.648 µM	27.118 µM	2012	[137]
Methomyl	Colorimetric	indoxyl acetate-R-DmAChE	0.005–45.197 µM0.006–61.648 µM	1.726 µM	2012	[137]
Carbaryl	Photoluminescence	SiQDs-AChE/ChOx	0.037–3722.29 nM	0.037 nM	2013	[195]
Carbaryl	Colorimetric	PABSA-AuNPs	0.100 nM–1 mM	0.250 µM	2013	[259]
Carbaryl	Fluorescence	CdSe/ZnSQDs	-	0.147 µM	2015	[260]
Metolcarb	Fluorescence	NOC4	0.100 nM–1.000 mM	0.100 µM	2015	[265]
Carbaryl	Chemiluminescent	Lum-AgNP	0–4.970 µM	4.970 µM	2015	[151]
Carbaryl			0–108.472 µM	108.472 µM
Carbofuran			0–108.472 µM	108.472 µM
Carbaryl	Colorimetric and chemiluminescent	dual-g-C₃N₄/BiFeO₃	0.005–0.298 µM	0.164 nM	2018	[192]
Carbofuran	SERS	AuNPs	0.005–45.197 µM	0.904 µM	2019	[153]
Carbofuran			0.006–61.648 µM	0.123 µM
Methomyl			0.006–61.648 µM	0.123 µM
Carbendazim	SERS	AuNPs	0–52.305 µM	0.523 µM	2019	[266]
Carbofuran	SPR	P(EGDMA-MATrp)	-	0.032 nM	2019	[234]
Carbendazim	SPR	AuNPs- Fe₃O₄/mAbs	0.262–784.572 nM	2.301 nM	2019	[267]
Aldicarb Carbofuran Carbofuran-3 hydroxy Carbaryl	Liquid Chromatography Tandem Mass Spectrometry	AChE	-	0.039 µM	2020	[138]
			-	0.007 µM
			-	5.901 pM
			-	0.007 µM
Carbaryl	HFF-QCM	mAbs	0.497 pM–4.970 nM	0.248 nM	2020	[261]
Carbaryl	Fluorescence	CdTeQDs	-	0.596 nM	2020	[262]
Carbaryl	Fluorescence	CQDs-AuNPs-AChE	0.994–745.453 nM	0.298 nM	2020	[263]
Carbaryl	Colorimetric	silver reduced-graphene oxide	0.100–50.000 μM	42.000 nM	2020	[264]

where LOD is limit of detection. CdSe: cadmium selenide, c[4]/SiO₂/CdTe: 5, 11, 17, 23-tetra-tert-butyl-25, 27-diethoxy-26, 28-dihydroxycalix[4]arene/ silicon dioxide/cadmium tellurite, g-C₃N₄/BiFeO₃: graphitic carbon nitrite/bismuth ferrite nanocomposite, HFF-QCM: high fundamental frequency quartz crystal microbalance, LFIA: lateral flow immunoassay, Lum-AgNP: luminol-functionalized silver nanoparticles, NOC4: naphthol-appended calix[4]arene, P(EGDMA-MATrp): ethylene glycol dimetacrylate-N-metacryloyl-(l)-tryptophan methyl ester-p, R-DMAChE: recombinant Drosophila melanogaster acetylcholinesterase, Re(I)-NCS-Pt(II): [Re(4,4′-di-tert-butyl-2,2′-bupryridine)(CO)₃(NCS)], SERS: surface-enhanced Raman spectroscopy, SiQDs: silicon quantum dots, PABSA: 4-acetamidobenzenesulfonyl azide, ZnSQDs: zinc selunide quantum dots.