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. 2021 Jun 2;12:677596. doi: 10.3389/fmicb.2021.677596

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Copyright © 2021 Mao, Yuan, Yang, Liu, Cheng, Luo, Liu, Yao, Sun, Cai and Ma.

This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.

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Identification of isomerized products from aldohexose 6-phosphates by GC-TOFMS method. (A) F6P standard. (B) Fragment distributions of ketohexose 6-phosphates produced via the isomerization of G6P, M6P, or A6P with retention times of 25.915, 26.018, and 26.094 min. (C) G6P standard and product from G6P catalyzed by Pgi. (D) M6P standard and product from M6P catalyzed by ManA. (E) Glk-based A6P and product from A6P catalyzed by RpiB (and AlsE). (F) Glk-based At6P and product from At6P catalyzed by Pgi, ManA, RpiB, and KdsD.