. 2021 Jun 3;143(23):8669–8678. doi: 10.1021/jacs.1c02275

Table 3. Dimerization Constants Measured by ITC Dilution Experiments in d₈-Toluene at 298 K^a.

sequence	log K(M^–1)	ΔG° (kJ mol^–1)	ΔH° (kJ mol^–1)	ΔS° (J K^–1 mol^–1)
AD	3.2	–18.3	–40	–77
AAD	3.1	–17.8	–39	–70
ADA	3.5	–20.2	–36	–54
ADD	3.3	–19.0	–36	–57
DAD	3.4	–19.2	–39	–67

Errors based on repeat experiments are 0.1 in log K, 0.5 kJ mol^–1 in ΔG°, 5 kJ mol^–1 in ΔH°, and 20 J K^–1 mol^–1 in ΔS°.

Table 3. Dimerization Constants Measured by ITC Dilution Experiments in d8-Toluene at 298 Ka.