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. 2021 Jun 8;12:670061. doi: 10.3389/fpls.2021.670061

Table 2.

Properties of usual polar aprotic solvents.

Properties Sulfolane DMSO NMP DMF DMAc THF Dioxane Acetone
Relative molecular mass 120.17 78.13 99.13 73.09 87.12 72.11 88.11 58.08
Density (g/cm3) 1.26 1.10 1.03 0.94 0.94 0.89 1.03 0.78
Boiling point (°C) 287.3 189.1 201.9 153.1 166.2 66 101.3 56.5
Freezing point (°C) 28.4 18.6 −24.4 −60.4 −20.1 −108 - −94
Dielectric constant (ɛv) 43.4a 46.7b 32.2b 36.7b 37.8b 7.58 2.51b 20.7
Dielectric loss (tanδ) - 0.825 0.275 0.161 - - - -
Dipole moment (debye) 4.69 3.96 4.09 3.8 3.72 1.75 0.45 2.85
Hildebrand parameters 27.2 26.6 23.6 24.1 23.3 - - -
Solvent polarity parameters 0.410 0.444 0.355 0.386 0.377 - - -
Viscosity (cP) 10.35a 2.0b 1.67b 0.9c 2.14c 0.55c 1.31c 0.32b
Flash point (°C) 177 89 86 58 63 −20 12 −20
Self-ignition point (°C) 528 302 270 445 445 321 180 465
Vapor pressure (kPa) 0.0091a 0.060b 0.050b 0.37b 0.13b 19.3c 5.33b 24.7c
a

30°C.

b

25°C.

c

20°C.