Table 2. Summary of Assignments of Main Vibrational Bands.
samples | HRP amide I (cm–1) | HRP amide II (cm–1)73 | CH2 bending/amino acids side chains (cm–1)74 | HRP amide III/amino acids side chains (cm–1)75 | HRP C–O, C–C, C–O–C (cm–1)74 | asymmetric PO43– (cm–1)76 | symmetric PO43– (cm–1)76 | H2O liberation (cm–1)77,78 |
---|---|---|---|---|---|---|---|---|
HRP powder | 1646 | 1544, 1527 | 1480, 1450 | 1388 | 1040, 1079 | |||
HRP solution | 1638 | 1551 | ||||||
Mn NPs, saline | 1645–1650 | 1538–1541 | 1451 | 1365–1370 | ||||
Mn NPs, PBS | 1017, 1047, 1098 | 997 | ||||||
Ni NPs, DMEM | 1650–1645 | 1554–1560 | 1412–1450 | 1299 | 1042–1045 | |||
Ni NPs, saline | 1640 | 1538 | 1433–1441 | 1304–1308 | 1008–1024 | |||
Ni NPs, PBS | 1650 | 1558/1510 | 1436 | 1308 | 1116, 1047 | 1116, 1047 | ||
Cu NPs, saline | 1636–1643a | 1535, 1520,1497 | 1444,1432, | 1386, 1292 | 890 | |||
Cu NPs, PBS | 1655a | 1538 | 1392, 1157 | 1005 | 890 |
Major contribution from H2O bending mode at ≈1643 cm–1