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. 2021 May 3;8(12):2100661. doi: 10.1002/advs.202100661

Table 1.

Summary of the constants characterizing the interaction of proteins with polyelectrolytes according to Equation (21)

System a) T 0 [K] Δn ci c p/dc s [kJ mol–1 K–1 m –1] ΔH 0 [kJ mol–1] ΔS 0 [kJ mol–1 K–1]
Heparin/lysozyme[ 54 ] 296 2.95 39.1 −41.70 −0.071
dPGS/lysozyme[ 38 ] 290 2.51 −14.8 −14.75 0.016
DNA/Klentaq[ 7 , 8 ] 312 3.0 −31.9 −22.30 0.011
a)

T 0: characteristic temperature (Equation (16)); Δn ci: net number of released counterions (Equation (4)); dΔc p/dc s: coefficient characterizing the dependence of Δw on temperature and salt concentration (Equation (15)); ΔH 0 and ΔS 0: enthalpic and entropic contributions, respectively, at T = T 0 (cf. Equations (14) and (20)).