Table 1.
System a) | T 0 [K] | Δn ci | dΔc p/dc s [kJ mol–1 K–1 m –1] | ΔH 0 [kJ mol–1] | ΔS 0 [kJ mol–1 K–1] |
---|---|---|---|---|---|
Heparin/lysozyme[ 54 ] | 296 | 2.95 | 39.1 | −41.70 | −0.071 |
dPGS/lysozyme[ 38 ] | 290 | 2.51 | −14.8 | −14.75 | 0.016 |
DNA/Klentaq[ 7 , 8 ] | 312 | 3.0 | −31.9 | −22.30 | 0.011 |
T 0: characteristic temperature (Equation (16)); Δn ci: net number of released counterions (Equation (4)); dΔc p/dc s: coefficient characterizing the dependence of Δw on temperature and salt concentration (Equation (15)); ΔH 0 and ΔS 0: enthalpic and entropic contributions, respectively, at T = T 0 (cf. Equations (14) and (20)).