Skip to main content
. Author manuscript; available in PMC: 2021 Jun 24.
Published in final edited form as: J Am Chem Soc. 2017 Jul 19;139(30):10526–10538. doi: 10.1021/jacs.7b05858

Figure 5.

Figure 5.

The structures of two conformations of the ammonium carbamate chains in Zn2(dobpdc)(m-2–CO2)1.62 at 100 K as determined by single-crystal X-ray diffraction. A primary ammonium forms in the first conformation (top, 29.2(9)% occupancy relative to ZnII), while a secondary ammonium forms in the second conformation (bottom, 51.7(9)% occupancy). Light blue, blue, red, gray, and white spheres represent Zn, N, O, C, and H atoms, respectively.