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. 2021 Mar 25;121(12):6744–6776. doi: 10.1021/acs.chemrev.0c01076

Table 6. Reaction between Ethyl Propiolate and Dodecanethiol Catalyzed by Triethylamine in Various Solvents at 0.1 M and Ambient Temperature76.

2.2.2.

solvent dielectric constant conversion (%) E/Z
C6H6 2.27 50 98/2
CHCl3 4.81 96 97/3
acetone 20.7 100 52/48
MeCNa 37.5 100 34/66
DMSOb 46.7 100 22/78
a

MeCN = acetonitrile.

b

DMSO = dimethylsulfoxide.