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. 2021 Mar 25;121(12):6744–6776. doi: 10.1021/acs.chemrev.0c01076

Table 8. Reaction of Methyl Propiolate with 2-Napthalenethiol Catalyzed by Various Inorganic Solids and Triethylamine in Diethyl Ether91.

2.2.3.

catalyst conversion (%) E/Z
none 19 50/50
Al2O3 96 10/90
SiO2 20 45/55
NEt3 85 58/42