Table 4.
Peak | Retention Time (min) | [M − H]− | Mass Fragmentation | Compound Name | References |
---|---|---|---|---|---|
1 | 1.11 | 195 | 177, 147, 129, 111, 99, 75 | Gluconic acid | Li et al. [19] Felipe et al. [20] |
2 | 1.52 | 191 | 173, 171, 127, 109, 93, 85, 65 | Quinic acid | Fathoni et al. [21] |
3 | 1.78 | 179 | 135, 107, 89, 59 | Caffeic acid | Li et al. [19] |
4 | 2.86 | 353 | 191, 179, 161, 135, 93, 85 | Chlorogenic acid | Li et al. [19] |
5 | 4.04 | 515 | 353, 85, 93, 135, 173, 179, 191, 161 | 3,4-Dicaffeoylquinic acid | Simirgiotis et al. [22] |
6 | 4.34 | 461 | 285, 133, 151, 175 | Luteolin-7-O-glucuronide | Li et al. [19] |
7 | 4.95 | 475 | 299, 284, 211, 227, 255 | Hispidulin-7-O-glucuronide | Li et al. [19] |
8 | 7.11 | 285 | 241, 217, 199, 175, 151, 133 | Luteolin | Fathoni et al. [21] |
Various phenolic acids and flavonoids in Erigeron annuus (L.) Pers. water extract (EAW) were determined by comparing retention time and mass spectra with reference standards. Peak number, refer to Figure 6.