Solution parameters |
Viscosity |
Low |
Discontinuation of filament formation, beads formation |
High |
Increase in fiber diameter, disappearance of beads, spinning prevention |
Polymer concentration |
|
Increase in fiber diameter with increase in concentration |
Molecular weight of polymer |
Lower |
Larger deposition area, smaller fibers, bead formation, appearance of droplets |
Higher |
Smaller deposition area, larger fibers |
Conductivity |
|
Decrease in fiber diameter with increase in conductivity |
Surface tension |
|
No conclusive link with fiber morphology, high surface tension results in instability of jets |
Processing parameters |
Applied voltage |
|
Decrease in fiber diameter with increase in voltage |
Distance between tip and collector |
|
Generation of beads with too small and too large distance, optimal distance is required for uniform fibers |
Flow rate |
Low |
Decrease in fiber diameter |
High |
Generation of beads with too-high flow rate |
Ambient parameters |
Humidity |
Low |
Broken filaments, nozzle clogging |
High |
High humidity results in circular pores on the fibers |
Temperature |
Low |
High viscosity and larger fiber diameter, nozzle clogging |
High |
Less viscosity and smaller fiber diameter, uniform formation of fibers |