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. 2021 Jun 11;11(6):1544. doi: 10.3390/nano11061544

Table 2.

Electrospinning parameters (solution, processing, and environment) and their effect on fiber morphology.

Parameters Effect on Fiber Morphology
Solution parameters Viscosity Low Discontinuation of filament formation, beads formation
High Increase in fiber diameter, disappearance of beads, spinning prevention
Polymer concentration Increase in fiber diameter with increase in concentration
Molecular weight of polymer Lower Larger deposition area, smaller fibers, bead formation, appearance of droplets
Higher Smaller deposition area, larger fibers
Conductivity Decrease in fiber diameter with increase in conductivity
Surface tension No conclusive link with fiber morphology, high surface tension results in instability of jets
Processing parameters Applied voltage Decrease in fiber diameter with increase in voltage
Distance between tip and collector Generation of beads with too small and too large distance, optimal distance is required for uniform fibers
Flow rate Low Decrease in fiber diameter
High Generation of beads with too-high flow rate
Ambient parameters Humidity Low Broken filaments, nozzle clogging
High High humidity results in circular pores on the fibers
Temperature Low High viscosity and larger fiber diameter, nozzle clogging
High Less viscosity and smaller fiber diameter, uniform formation of fibers