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. 2021 Jun 12;14(12):3253. doi: 10.3390/ma14123253

Table 2.

Milestone chronology in coating history [35,36,37,38].

Year/Period Event Description
Pre-History
Before 4000 B.C Varnishes and paints were used during the stone age art
Before 6000 BC Development of organic pigments (gum Arabic, egg white, gelatin, and beeswax)
Since 5000 BC Use of protective coatings by Egyptians to seal ships
Ancient Age
1300 B.C-1400 B.C Use of oleo-resinous varnishes by Egyptians
Since 1122 BC Introduction of polymers as the main component in coatings
350 B.C First written record of uses of varnishes
Middle Age
476 B.C-1453 Use of different organic paints and varnishes for the protection of exposed wood surfaces
Modern Age
1550–1750 Researches about coatings for protection of musical instruments made in wood
1575 The first use of yellow amber resin as a primary component in coatings
Since 1760 Significant emergence of coating materials as a high technology industry, the development of synthetic resins in solutions, emulsion, latexes, and waterborne polymers
1763 First varnish patent
Contemporary Age
1815 Start industrial varnish production
1839 The first production of styrene monomer used as a modifier in polymer coatings
1910 Casein powder paints
1912 Patented acrylic resin
1939–1945 Development of alkyds, urethane, and epoxy resins
1948 Incorporation of latex resins in the coating industry
1961–1965 Development of coil coatings, electrodeposition curtain coating, computer color control electrostatic powder spray, fluorocarbon resins
1970 Use of emulsion resin to control penetration in substrates
1966–1970 Development of radiation curable coatings
1970–1975 Development of aqueous industrial enamels electron beam curing, and ultraviolet curing
1976–1980 Development of high solid epoxy and polyurethane coatings resins
1981–1985 Development of high-performance pigments, polyurea resins, and high solids alkyd paints
1986–1999 Waterborne epoxy coatings and waterborne polyurethanes
21st Century New systems based on alkyd technology, synthetic polymer-based coating resins, e.g., PVC-plastisol, acrylate dispersion, melamine/polyester, 2K urethanes, and inclusion of new drier systems for alkyds by replacing the cobalt driers