Table 1. Concentration of Hydroxyl (Aliphatic, Phenolic) and Carboxylic Groups (mmol/glignin) as Obtained from Quantitative 31P NMR Analysis; Number Average Molecular Weight (Mn) and Polydispersity Index (Đ) as Obtained from GPC Analysis; Reported Values Refer to Pristine (PL) and Oxidized (OL) Lignins.
OH content (mmol/g) |
||||||
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sample | aliphatic (Aliph-OH) | phenolic (Ph-OH) | carboxylic (−COOH) | totala | Mn (g/mol) | Đ |
PL | 2.11 | 3.55 | 0.33 | 5.99 | 1810 | 2.3 |
OL | 2.59 | 4.56 | 0.43 | 7.58 | 1460 | 1.9 |
Aliph-OH, Ph-OH, and −COOH groups were considered.