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. 2021 May 25;1(6):865–878. doi: 10.1021/jacsau.1c00078

Table 1. Reduction Potential Values (E1/2) vs Normal Hydrogen Electrode (NHE) for Metal Complexes Involved in the Fe(III) Transmetalation of [Ti(Def)2]2– and [TiO(H+–HBED)] at pH 7.4a.

compound E1/2 (V)
[Ti(Def)2]2– –0.77
[TiO(H+–HBED)] –0.60
[Fe(Def)2]3– –0.59
[Fe(HBED)] –0.28
[Fe(Cit)2]5– –0.38* and 0.16*
[Fe(Cit)(Def)]4– –0.75*, −0.41*, 0.19*
a

* represents peak potential values of the cathodic peak (Ec) due to a mixture of species.