Table 1. Reduction Potential Values (E1/2) vs Normal Hydrogen Electrode (NHE) for Metal Complexes Involved in the Fe(III) Transmetalation of [Ti(Def)2]2– and [TiO(H+–HBED)]− at pH 7.4a.
compound | E1/2 (V) |
---|---|
[Ti(Def)2]2– | –0.77 |
[TiO(H+–HBED)]− | –0.60 |
[Fe(Def)2]3– | –0.59 |
[Fe(HBED)]− | –0.28 |
[Fe(Cit)2]5– | –0.38* and 0.16* |
[Fe(Cit)(Def)]4– | –0.75*, −0.41*, 0.19* |
* represents peak potential values of the cathodic peak (Ec) due to a mixture of species.