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. 2021 May 13;12(25):8803–8810. doi: 10.1039/d1sc00619c

Comparisons of equilibrium CO2 uptake and selectivity on various zeolites and SAPOs.

Material CO2 uptake [mmol g−1] CH4 uptake [mmol g−1] N2 uptake [mmol g−1] α(CO2/CH4) (0.02/0.98 bar) α(CO2/N2) (0.15/0.85 bar) Ref.
0.02 bar 0.15 bar 1.0 bar 0.98 bar 0.85 bar
H-SAPO-RHOa 0.44 1.84 4.41 0.83 0.210 26 50 This work
Na-SAPO- RHO a 1.21 2.42 3.53 0.027 0.070 2196 196 This work
K-SAPO-RHOa 0.01 0.046 0.87 0.024 0.010 20 29 This work
Cs-SAPO-RHOa 0.01 0.054 0.45 0.017 0.014 30 22 This work
Na-1-SAPO-RHOa 0.81 2.04 3.43 0.090 0.116 441 105 This work
Na-2-SAPO-RHOa 0.71 2.28 3.38 0.042 0.089 828 145 This work
Na-4-SAPO-RHOa 0.60 1.82 3.08 0 0 This work
H-SAPO-RHOa 0.49 1.95 4.60 0.38 0.23 63 48 24
SAPO-34b 0.24 1.20 3.26 0.65 20 25
Na-SAPO-34b 0.89 2.10 3.40 0.62 0.26 75 44 25
SAPO-17c 0.29 1.29 3.27 0.31 23 26
SAPO-35c 0.29 1.87 3.68 0.32 33 26
SAPO-56c 0.76 2.87 5.44 0.39 42 26
Na-RHOa 2.06 3.30 4.23 0.11 960 15a
Na-CHAa 2.64 3.95 4.70 1.60 0.60 81 37 27
Na-KFId 3.40 0.27 71 28
Na-Xa 2.00 3.17 5.00 0.67 0.23 147 78 29
Na-MERa 1.50 2.50 3.80 0.32 229 30
K-MERa 1.93 2.93 3.57 0.052 1818 30
NaKA (K = 17%)a 1.00 2.30 3.43 0.02 660 22
Na-Aa 3.20 3.90 4.80 1.34 0.65 117 34 31
Mg-MOF-74a 2.30 5.65 8.00 1.11 102 32
SIFSIX-3-Zna 1.95 2.30 2.55 0.79 0.46 121 28 32a
UTSA-280a 0.48 1.58 2.78 0.10 0.15 235 60 33
a

The adsorption data were measured at 298 K.

b

The adsorption data were measured at 293 K.

c

The adsorption data were measured at 273 K.

d

The adsorption data were measured at 303 K.