Comparisons of equilibrium CO2 uptake and selectivity on various zeolites and SAPOs.
Material | CO2 uptake [mmol g−1] | CH4 uptake [mmol g−1] | N2 uptake [mmol g−1] | α(CO2/CH4) (0.02/0.98 bar) | α(CO2/N2) (0.15/0.85 bar) | Ref. | ||
---|---|---|---|---|---|---|---|---|
0.02 bar | 0.15 bar | 1.0 bar | 0.98 bar | 0.85 bar | ||||
H-SAPO-RHOa | 0.44 | 1.84 | 4.41 | 0.83 | 0.210 | 26 | 50 | This work |
Na-SAPO- RHO a | 1.21 | 2.42 | 3.53 | 0.027 | 0.070 | 2196 | 196 | This work |
K-SAPO-RHOa | 0.01 | 0.046 | 0.87 | 0.024 | 0.010 | 20 | 29 | This work |
Cs-SAPO-RHOa | 0.01 | 0.054 | 0.45 | 0.017 | 0.014 | 30 | 22 | This work |
Na-1-SAPO-RHOa | 0.81 | 2.04 | 3.43 | 0.090 | 0.116 | 441 | 105 | This work |
Na-2-SAPO-RHOa | 0.71 | 2.28 | 3.38 | 0.042 | 0.089 | 828 | 145 | This work |
Na-4-SAPO-RHOa | 0.60 | 1.82 | 3.08 | 0 | 0 | ∞ | ∞ | This work |
H-SAPO-RHOa | 0.49 | 1.95 | 4.60 | 0.38 | 0.23 | 63 | 48 | 24 |
SAPO-34b | 0.24 | 1.20 | 3.26 | 0.65 | — | 20 | — | 25 |
Na-SAPO-34b | 0.89 | 2.10 | 3.40 | 0.62 | 0.26 | 75 | 44 | 25 |
SAPO-17c | 0.29 | 1.29 | 3.27 | — | 0.31 | — | 23 | 26 |
SAPO-35c | 0.29 | 1.87 | 3.68 | — | 0.32 | — | 33 | 26 |
SAPO-56c | 0.76 | 2.87 | 5.44 | — | 0.39 | — | 42 | 26 |
Na-RHOa | 2.06 | 3.30 | 4.23 | 0.11 | — | 960 | — | 15a |
Na-CHAa | 2.64 | 3.95 | 4.70 | 1.60 | 0.60 | 81 | 37 | 27 |
Na-KFId | — | 3.40 | — | — | 0.27 | — | 71 | 28 |
Na-Xa | 2.00 | 3.17 | 5.00 | 0.67 | 0.23 | 147 | 78 | 29 |
Na-MERa | 1.50 | 2.50 | 3.80 | 0.32 | — | 229 | — | 30 |
K-MERa | 1.93 | 2.93 | 3.57 | 0.052 | — | 1818 | — | 30 |
NaKA (K = 17%)a | 1.00 | 2.30 | 3.43 | — | 0.02 | — | 660 | 22 |
Na-Aa | 3.20 | 3.90 | 4.80 | 1.34 | 0.65 | 117 | 34 | 31 |
Mg-MOF-74a | 2.30 | 5.65 | 8.00 | 1.11 | — | 102 | — | 32 |
SIFSIX-3-Zna | 1.95 | 2.30 | 2.55 | 0.79 | 0.46 | 121 | 28 | 32a |
UTSA-280a | 0.48 | 1.58 | 2.78 | 0.10 | 0.15 | 235 | 60 | 33 |
The adsorption data were measured at 298 K.
The adsorption data were measured at 293 K.
The adsorption data were measured at 273 K.
The adsorption data were measured at 303 K.